题目内容

化合物A分子式C6H12O,能够与羟胺反应,而与Tollen’s试剂以及饱和亚硫酸氢钠溶液都不反应。A催化加氢能得到B,B的分子式是C6H14O,B和浓硫酸脱水作用能够得到C,C的分子式C6H12,C经过臭氧化,在锌还原性水解条件下生成D和E,两者的分子式均为C3H6O。D有碘仿反应而无银镜反应,E有银镜反应而无碘仿反应。推测A,B,C,D,E的结构。

A. CH3CH2CHOHCH(CH3)2
B. CH3CH2CH=C(CH3)2
CH3COCH3
D. CH3CH2CHO

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