题目内容

In the 1H NMR spectrum of CH3CH2OCH(CH3)2, the ratio of area of various proton signals is 9:2:1.

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The hydrogen bond has a great influence on the proton chemical shift of active hydrogen.

In the infrared spectrum, there are two obvious absorption bands in the range of 3500~3100 cm-1, then the most likely compound is( )

A. (C6H5)CONH(C6H5)
B. (C6H5)COOH
C. (C6H5)CO(C6H5)
D. (C6H5)CONH2

In the infrared spectrum, the absorption peak in the high frequency region near 3000 cm-1 is mainly caused by( )

A. stretching vibration of C-C, C-O
B. stretching vibration of C-H, O-H, N-H
C. stretching vibration of C=C, C=O
D. stretching vibration of C≡C, C≡N

In alcohol compounds, due to the strengthening of the intermolecular hydrogen bond, the O-H stretching vibration frequency ( ) with the increase of the solution concentration.

A. moves towards low wavenumber
B. moves towards high wavenumber
C. No change
D. A and B are both possible

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