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1H NMR spectrum of a compound (C5H10O) shows only two single peaks. The structural formula of the compound should be ( ).

A. CH3CH2CH2COCH3
B. (CH3)2CHCOCH3
C. (CH3)3CCHO
D. CH3CH2COCH2CH3

Among -OCH3, -CCH3, and -NCH3, -NCH3 displays the largest proton chemical shift in NMR spectrum.

In the mass spectrum of bromoethane, two ion peaks of equal intensity are observed, the most likely ones are ( ).

A. m/z 19 and 25
B. m/z 95 and 93
C. m/z 29 and 95
D. m/z 93 and 15

If a strong peak of m/z = 31 appears in the mass spectrum of a compound, the compound cannot be an amine.