The glass transition occurs in ______ regions of polymers.
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Upon cooling, this phenomenon corresponds to the gradual transformation from a liquid into a rubbery material, and finally into a rigid solid. With decreasing temperature there is a reduction in the ______ of large segments of molecular chains.
The magnitudes of Tm and Tg increase with increasing chain stiffness; stiffness is enhanced by the presence of chain double bonds and side ______ that are either bulky or polar.
At low molecular weights Tm and Tg ______ with increasing molecular weight.
One way of classifying polymeric materials is according to their end use.With this scheme, the several types include ______ , fibers, coatings, adhesives, films, foams, and advanced materials.